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2-Methylanisole, 99%, Thermo Scientific Chemicals Product Code.: 11491598
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2-Methylanisole, 99%, Thermo Scientific Chemicals

Product Code. 11491598
50 g
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Product Code. 11491598

Brand: Thermo Scientific Alfa Aesar A13897.18

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Description

The catalytic system of disubstituted aromatics was optimized for the 2-methylanisole reduction by a proper choice of the amine/Rh ratio which should be high enough to stabilize very small colloidal rhodium particles and low enough to avoid deactivation. The total synthesis of (±)-heliannuol D and its epimer has been completed in 9 steps and 12% overall yield from 2-methylanisole. The thermal activation of 2-methylanisole (60°C) by the Ir (III) complex TpMe2Ir (C6H5) 2 (N2)(1; TpMe2= hydrotris (3, 5-dimethylpyrazolyl) borate) yielded a mixture of hydride complexes. The total synthesis of the phenolic sesquiterpene mutisianthol has been accomplished in 12 steps from the readily available 2-methylanisole. The catalytic system was optimized for the 2-methylanisole reduction by a proper choice of the amine/Rh ratio which should be high enough to stabilize very small colloidal rhodium particles and low enough to avoid deactivation.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
The catalytic system of disubstituted aromatics was optimized for the 2-methylanisole reduction by a proper choice of the amine/Rh ratio which should be high enough to stabilize very small colloidal rhodium particles and low enough to avoid deactivation. The total synthesis of (±)-heliannuol D and its epimer has been completed in 9 steps and 12% overall yield from 2-methylanisole. The thermal activation of 2-methylanisole (60°C) by the Ir (III) complex TpMe2Ir (C6H5) 2 (N2)(1; TpMe2= hydrotris (3, 5-dimethylpyrazolyl) borate) yielded a mixture of hydride complexes. The total synthesis of the phenolic sesquiterpene mutisianthol has been accomplished in 12 steps from the readily available 2-methylanisole. The catalytic system was optimized for the 2-methylanisole reduction by a proper choice of the amine/Rh ratio which should be high enough to stabilize very small colloidal rhodium particles and low enough to avoid deactivation.

Solubility
Insoluble in water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 578-58-5
Molecular Formula C8H10O
Molecular Weight (g/mol) 122.167
MDL Number MFCD00008373
InChI Key DTFKRVXLBCAIOZ-UHFFFAOYSA-N
Synonym 2-methylanisole, o-methylanisole, 2-methoxytoluene, o-cresol methyl ether, o-cresyl methyl ether, anisole, o-methyl, benzene, 1-methoxy-2-methyl, methyl o-tolyl ether, o-methoxytoluene, 2-methylmethoxybenzeneShow MoreShow Less
PubChem CID 33637
IUPAC Name 1-methoxy-2-methylbenzene
SMILES CC1=CC=CC=C1OC

Specifications

Density 0.985
Boiling Point 170°C to 172°C
Flash Point 51°C (123°F)
Refractive Index 1.517
Quantity 50 g
UN Number UN3271
Beilstein 1857415
Solubility Information Insoluble in water.
Formula Weight 122.17
Percent Purity 99%
Chemical Name or Material 2-Methylanisole
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5 results found
Lot Number Certificate Type Date Catalog Number
Lot Number10245184 Certificate TypeCertificate of Analysis Date05/01/2023 Catalog NumberA13897.18,A13897.30
Lot Number10239967 Certificate TypeCertificate of Analysis Date12/04/2022 Catalog NumberA13897.18,A13897.30
Lot Number10169835 Certificate TypeCertificate of Analysis Date22/11/2021 Catalog NumberA13897.18,A13897.30
Lot Number10213700 Certificate TypeCertificate of Analysis Date22/11/2021 Catalog NumberA13897.18,A13897.30
Lot Number10210178 Certificate TypeCertificate of Analysis Date22/11/2021 Catalog NumberA13897.18,A13897.30

Safety and Handling

compliance-icons
Product Identifier
  • 2-Methylanisole
 Signal Word
  • Warning
 Hazard Category
  • Flammable liquid Category 3
 Hazard Statement
  • H226-Flammable liquid and vapour.
 Precautionary Statement
  • P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
 Supplemental information
  • MIXTURE LIST-Contains : 2-Methylanisole
SDS

RUO – Research Use Only

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