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Nitrosonium tetrafluoroborate, 98%, Thermo Scientific Chemicals
Description
Nitrosonium tetrafluoroborate is a nitrosating agent and oxidizer used in organic synthesis. It is also used to convert arylamines directly to diazonium tetrafluoroborates, which undergo the Balz-Schiemann reaction in situ to give high yields of aryl fluorides. Further, it is used as a catalyst for iodination of aromatics by iodide ion with air as oxidant, conversion of secondary amines to nitrosamines and in deamination of primary amides. It is involved in the conversion of arylhydrazines to azides. In addition to this, it reacts with ferrocene to prepare ferrocenium tetrafluoroborate.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Nitrosonium tetrafluoroborate is a nitrosating agent and oxidizer used in organic synthesis. It is also used to convert arylamines directly to diazonium tetrafluoroborates, which undergo the Balz-Schiemann reaction in situ to give high yields of aryl fluorides. Further, it is used as a catalyst for iodination of aromatics by iodide ion with air as oxidant, conversion of secondary amines to nitrosamines and in deamination of primary amides. It is involved in the conversion of arylhydrazines to azides. In addition to this, it reacts with ferrocene to prepare ferrocenium tetrafluoroborate.
Solubility
Soluble in acetonitrile.
Notes
Hygroscopic. Air and moisture sensitive. Store in a cool place. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with acids and amines.
Specifications
Specifications
| Boiling Point | 250°C (0.01 mmHg)(Sublimation) |
| Melting Point | 250°C (Sublimation) |
| Quantity | 2 g |
| UN Number | UN3260 |
| Merck Index | 14,6649 |
| Solubility Information | Soluble in acetonitrile. |
| Formula Weight | 116.82 |
| Percent Purity | 98% |
| Odor | Irritating |
| Sensitivity | Moisture sensitive |
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Safety and Handling
- Nitrosonium tetrafluoroborate
- Danger
- Serious eye damage/eye irritation Category 1
- Skin corrosion/irritation Category 1 B
- H314-Causes severe skin burns and eye damage.
- H318-Causes serious eye damage.
- EUH031-Contact with acids liberates toxic gas.
- P280-Wear protective gloves/protective clothing/eye protection/face protection.
- P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
- P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P310-Immediately call a POISON CENTER/doctor/.
- MIXTURE LIST-Contains : Nitrosonium tetrafluoroborate
RUO – Research Use Only
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