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Di-tert-butylchlorophosphine, 96%, Thermo Scientific Chemicals Product Code.: 11335349
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Di-tert-butylchlorophosphine, 96%, Thermo Scientific Chemicals

Product Code. 11335349
25 g
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1 g
5 g
25 g
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Product Code. 11335349

Brand: Thermo Scientific Alfa Aesar B20998.14

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Description

Di-tert-butylchlorophosphine is associated with palladium(II) acetate and used in Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides. It serves as a ligand and used in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations. Further, it is used in asymmetric and transition metal coupling reactions. In addition to this, it plays an important role in the preparation of other phosphines in catalytic polymerization reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Di-tert-butylchlorophosphine is associated with palladium(II) acetate and used in Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides. It serves as a ligand and used in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations. Further, it is used in asymmetric and transition metal coupling reactions. In addition to this, it plays an important role in the preparation of other phosphines in catalytic polymerization reactions.

Solubility
Miscible with terahydrofuran.

Notes
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and strong reducing agents.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 13716-10-4
Molecular Formula C8H18ClP
Molecular Weight (g/mol) 180.656
MDL Number MFCD00008815
InChI Key MCRSZLVSRGTMIH-UHFFFAOYSA-N
Synonym di-tert-butylchlorophosphine, di-tert-butylchlorophosphane, di-t-butylchlorophosphine, phosphinous chloride, bis 1,1-dimethylethyl, chlorodi-tert-butylphosphine, phosphinous chloride, di-tert-butyl, di-tert-butyl chloro phosphane, di-tert-butylphosphinous chloride, clptbu2, pubchem6477
PubChem CID 139566
IUPAC Name ditert-butyl(chloro)phosphane
SMILES CC(C)(C)P(C(C)(C)C)Cl

Specifications

Density 0.951
Boiling Point 47°C to 49°C (3 mmHg)
Flash Point 62°C (144°F)
Odor Acrid
Linear Formula [(CH3)3C]2PCl
Refractive Index 1.484
Quantity 25 g
UN Number UN3265
Sensitivity Air and moisture sensitive
Solubility Information Miscible with terahydrofuran.
Formula Weight 180.66
Percent Purity 96%
Chemical Name or Material Di-tert-butylchlorophosphine
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Certificates

Certificates

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5 results found
Lot Number Certificate Type Date Catalog Number
Lot NumberA0461234 Certificate TypeCertificate of Analysis Date29/11/2024 Catalog NumberB20998.06,B20998.14
Lot NumberA0450878 Certificate TypeCertificate of Analysis Date03/01/2024 Catalog NumberB20998.06,B20998.14
Lot Number10229894 Certificate TypeCertificate of Analysis Date05/05/2023 Catalog NumberB20998.06,B20998.14
Lot Number10225286 Certificate TypeCertificate of Analysis Date01/05/2023 Catalog NumberB20998.06,B20998.14
Lot Number10225286 Certificate TypeCertificate of Analysis Date23/11/2021 Catalog NumberB20998.06,B20998.14

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